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Chars and Activated Carbons Prepared from Asturian Apple Pulp

机译:从阿斯图里亚斯苹果浆制得的炭和活性炭

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摘要

Asturian apple pulp was carbonised under nitrogen at 400ºC and 750ºC and subsequently activated with CO at 750ºC. The resulting active carbon exhibited properties in line with those expected from precursors of vegetable origin, with the carbonisation stage appearing to have only a limited influence on the final porosity. In the case of carbonisation at 400ºC, the initial micropore system of the char was accessible to dichloromethane, CO and water, but presented a strong gate effect at ca. 0.35-0.40 nm. The pore volume, W, was equal to 0.13 cm/g and the average pore width 0.70 nm. The pore size distribution was obtained from CO adsorption at 0ºC, using isotherms derived from computer modelling. With the char prepared at 750ºC, the initial porosity was only accessible to water and its presence was confirmed by extrapolation of W for the activated carbons.
机译:阿斯图里亚斯苹果浆在氮气下于400ºC和750ºC碳化,然后在750ºC用CO活化。所得的活性炭表现出与植物来源的前体所期望的特性一致的特性,并且碳化阶段似乎对最终孔隙率仅具有有限的影响。在400ºC碳化的情况下,焦炭的初始微孔系统可与二氯甲烷,CO和水接触,但在约200℃时表现出很强的门效应。 0.35-0.40纳米。孔体积W等于0.13cm / g,平均孔宽度0.70nm。孔径分布是通过使用计算机建模得出的等温线从0ºC下的CO吸附获得的。在750ºC的温度下制备焦炭时,初始孔隙率仅可通过水获得,并且通过W对活性炭的外推法可以证实其存在。

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